In steps:
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I opened the Session / New Connection dialog
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I have a lot of Databases and users already saved there. I select one of the Users in one database, check the box “Save Pwd” and click on the Button “Connect”
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TOAD ask me to enter the Password in a small window.
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I enter the Password and TOAD connects me to the database
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I close TOAD and open it again
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Again i open Session / New Connection, select the same user from above, but TOAD again ask me for the Password !?